AN ACCURATE CALCULATION OF THE GROUND-STATE ENERGY OF THE HELIUM ATOM AND THE HYDROGEN NEGATIVE-ION USING HYPERSPHERICAL COORDINATES
The method of hyperspherical harmonics using an adiabatic separation between the hyper-radial coordinate and the hyperspherical angles is applied to the calculation of the ground state of the helium atom and the hydrogen negative ion. For each system the simple adiabatic separation provides much of...
| Main Authors: | , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
1987
|
| _version_ | 1797087931159019520 |
|---|---|
| author | Frey, J Howard, B |
| author_facet | Frey, J Howard, B |
| author_sort | Frey, J |
| collection | OXFORD |
| description | The method of hyperspherical harmonics using an adiabatic separation between the hyper-radial coordinate and the hyperspherical angles is applied to the calculation of the ground state of the helium atom and the hydrogen negative ion. For each system the simple adiabatic separation provides much of the electron correlation energy. The non-adiabatic coupling is included by means of a perturbation treatment using both the Rayleigh-Schrödinger and Brillouin-Wigner approaches. These provide rapid convergence to the exact energy of -2.90372 au. © 1987. |
| first_indexed | 2024-03-07T02:42:36Z |
| format | Journal article |
| id | oxford-uuid:aaf420d7-384c-4f95-9ae8-f58bc9c2e6ee |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:42:36Z |
| publishDate | 1987 |
| record_format | dspace |
| spelling | oxford-uuid:aaf420d7-384c-4f95-9ae8-f58bc9c2e6ee2022-03-27T03:18:41ZAN ACCURATE CALCULATION OF THE GROUND-STATE ENERGY OF THE HELIUM ATOM AND THE HYDROGEN NEGATIVE-ION USING HYPERSPHERICAL COORDINATESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:aaf420d7-384c-4f95-9ae8-f58bc9c2e6eeEnglishSymplectic Elements at Oxford1987Frey, JHoward, BThe method of hyperspherical harmonics using an adiabatic separation between the hyper-radial coordinate and the hyperspherical angles is applied to the calculation of the ground state of the helium atom and the hydrogen negative ion. For each system the simple adiabatic separation provides much of the electron correlation energy. The non-adiabatic coupling is included by means of a perturbation treatment using both the Rayleigh-Schrödinger and Brillouin-Wigner approaches. These provide rapid convergence to the exact energy of -2.90372 au. © 1987. |
| spellingShingle | Frey, J Howard, B AN ACCURATE CALCULATION OF THE GROUND-STATE ENERGY OF THE HELIUM ATOM AND THE HYDROGEN NEGATIVE-ION USING HYPERSPHERICAL COORDINATES |
| title | AN ACCURATE CALCULATION OF THE GROUND-STATE ENERGY OF THE HELIUM ATOM AND THE HYDROGEN NEGATIVE-ION USING HYPERSPHERICAL COORDINATES |
| title_full | AN ACCURATE CALCULATION OF THE GROUND-STATE ENERGY OF THE HELIUM ATOM AND THE HYDROGEN NEGATIVE-ION USING HYPERSPHERICAL COORDINATES |
| title_fullStr | AN ACCURATE CALCULATION OF THE GROUND-STATE ENERGY OF THE HELIUM ATOM AND THE HYDROGEN NEGATIVE-ION USING HYPERSPHERICAL COORDINATES |
| title_full_unstemmed | AN ACCURATE CALCULATION OF THE GROUND-STATE ENERGY OF THE HELIUM ATOM AND THE HYDROGEN NEGATIVE-ION USING HYPERSPHERICAL COORDINATES |
| title_short | AN ACCURATE CALCULATION OF THE GROUND-STATE ENERGY OF THE HELIUM ATOM AND THE HYDROGEN NEGATIVE-ION USING HYPERSPHERICAL COORDINATES |
| title_sort | accurate calculation of the ground state energy of the helium atom and the hydrogen negative ion using hyperspherical coordinates |
| work_keys_str_mv | AT freyj anaccuratecalculationofthegroundstateenergyoftheheliumatomandthehydrogennegativeionusinghypersphericalcoordinates AT howardb anaccuratecalculationofthegroundstateenergyoftheheliumatomandthehydrogennegativeionusinghypersphericalcoordinates AT freyj accuratecalculationofthegroundstateenergyoftheheliumatomandthehydrogennegativeionusinghypersphericalcoordinates AT howardb accuratecalculationofthegroundstateenergyoftheheliumatomandthehydrogennegativeionusinghypersphericalcoordinates |