Consecutive alkene cross-metathesis/oxonium ylide formation-rearrangement: synthesis of the anti-HIV agent hyperolactone C.

Alpha-diazo-beta-ketoesters bearing allylic ether functionality undergo highly stereoselective Ru-carbene-catalyzed alkene cross-metathesis followed by Rh(2)(OAc)(4)-catalyzed oxonium ylide formation/[2,3] sigmatropic rearrangement in a one-flask operation and in a highly diastereoselective manner....

詳細記述

書誌詳細
主要な著者: Hodgson, D, Angrish, D, Erickson, S, Kloesges, J, Lee, C
フォーマット: Journal article
言語:English
出版事項: 2008