Anodic stripping voltammetry of arsenic(III) using gold nanoparticle-modified electrodes.

A novel method for the detection of arsenic(III) in 1 M HCl at a gold nanoparticle-modified glassy carbon electrode has been developed. The gold nanoparticles were electrodeposited onto the glassy carbon electrode via a potential step from +1.055 to -0.045 V vs SCE for 15 s from 0.5 M H2SO4 containi...

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Main Authors: Dai, X, Nekrassova, O, Hyde, M, Compton, R
Format: Journal article
Language:English
Published: 2004
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author Dai, X
Nekrassova, O
Hyde, M
Compton, R
author_facet Dai, X
Nekrassova, O
Hyde, M
Compton, R
author_sort Dai, X
collection OXFORD
description A novel method for the detection of arsenic(III) in 1 M HCl at a gold nanoparticle-modified glassy carbon electrode has been developed. The gold nanoparticles were electrodeposited onto the glassy carbon electrode via a potential step from +1.055 to -0.045 V vs SCE for 15 s from 0.5 M H2SO4 containing 0.1 mM HAuCl4. The resulting electrode surfaces were characterized with both AFM and cyclic voltammetry. Anodic stripping voltammetry of arsenic(III) on the modified electrode was performed. After optimization, a LOD of 0.0096 ppb was obtained with LSV.
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spelling oxford-uuid:ab926d05-672f-4999-9d28-9cba2de7fb162022-03-27T03:22:53ZAnodic stripping voltammetry of arsenic(III) using gold nanoparticle-modified electrodes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ab926d05-672f-4999-9d28-9cba2de7fb16EnglishSymplectic Elements at Oxford2004Dai, XNekrassova, OHyde, MCompton, RA novel method for the detection of arsenic(III) in 1 M HCl at a gold nanoparticle-modified glassy carbon electrode has been developed. The gold nanoparticles were electrodeposited onto the glassy carbon electrode via a potential step from +1.055 to -0.045 V vs SCE for 15 s from 0.5 M H2SO4 containing 0.1 mM HAuCl4. The resulting electrode surfaces were characterized with both AFM and cyclic voltammetry. Anodic stripping voltammetry of arsenic(III) on the modified electrode was performed. After optimization, a LOD of 0.0096 ppb was obtained with LSV.
spellingShingle Dai, X
Nekrassova, O
Hyde, M
Compton, R
Anodic stripping voltammetry of arsenic(III) using gold nanoparticle-modified electrodes.
title Anodic stripping voltammetry of arsenic(III) using gold nanoparticle-modified electrodes.
title_full Anodic stripping voltammetry of arsenic(III) using gold nanoparticle-modified electrodes.
title_fullStr Anodic stripping voltammetry of arsenic(III) using gold nanoparticle-modified electrodes.
title_full_unstemmed Anodic stripping voltammetry of arsenic(III) using gold nanoparticle-modified electrodes.
title_short Anodic stripping voltammetry of arsenic(III) using gold nanoparticle-modified electrodes.
title_sort anodic stripping voltammetry of arsenic iii using gold nanoparticle modified electrodes
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AT nekrassovao anodicstrippingvoltammetryofarseniciiiusinggoldnanoparticlemodifiedelectrodes
AT hydem anodicstrippingvoltammetryofarseniciiiusinggoldnanoparticlemodifiedelectrodes
AT comptonr anodicstrippingvoltammetryofarseniciiiusinggoldnanoparticlemodifiedelectrodes