4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside.
The title compound, C(21)H(26)O(10)S, was synthesized in a single step from mannose penta-acetate. The mol-ecular structure confirms the α configuration of the anomeric thioaryl substituent. Spectroscopic and melting-point data obtained for the title compound are in disagreement with those previousl...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2008
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| _version_ | 1826290643929923584 |
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| author | Drouin, L Cowley, A Fairbanks, A Thompson, A |
| author_facet | Drouin, L Cowley, A Fairbanks, A Thompson, A |
| author_sort | Drouin, L |
| collection | OXFORD |
| description | The title compound, C(21)H(26)O(10)S, was synthesized in a single step from mannose penta-acetate. The mol-ecular structure confirms the α configuration of the anomeric thioaryl substituent. Spectroscopic and melting-point data obtained for the title compound are in disagreement with those previously reported, indicating the previously reported synthesis [Durette and Shen (1980 ▶). Carbohydr. Res. 81, 261-274] to be erroneous. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds. |
| first_indexed | 2024-03-07T02:47:20Z |
| format | Journal article |
| id | oxford-uuid:ac785e6d-db0a-4a22-9c6c-cf0300668207 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:47:20Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:ac785e6d-db0a-4a22-9c6c-cf03006682072022-03-27T03:29:16Z4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ac785e6d-db0a-4a22-9c6c-cf0300668207EnglishSymplectic Elements at Oxford2008Drouin, LCowley, AFairbanks, AThompson, AThe title compound, C(21)H(26)O(10)S, was synthesized in a single step from mannose penta-acetate. The mol-ecular structure confirms the α configuration of the anomeric thioaryl substituent. Spectroscopic and melting-point data obtained for the title compound are in disagreement with those previously reported, indicating the previously reported synthesis [Durette and Shen (1980 ▶). Carbohydr. Res. 81, 261-274] to be erroneous. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds. |
| spellingShingle | Drouin, L Cowley, A Fairbanks, A Thompson, A 4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside. |
| title | 4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside. |
| title_full | 4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside. |
| title_fullStr | 4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside. |
| title_full_unstemmed | 4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside. |
| title_short | 4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside. |
| title_sort | 4 methoxy phenyl 2 3 4 6 tetra o acetyl 1 thio α d mannopyran oside |
| work_keys_str_mv | AT drouinl 4methoxyphenyl2346tetraoacetyl1thioadmannopyranoside AT cowleya 4methoxyphenyl2346tetraoacetyl1thioadmannopyranoside AT fairbanksa 4methoxyphenyl2346tetraoacetyl1thioadmannopyranoside AT thompsona 4methoxyphenyl2346tetraoacetyl1thioadmannopyranoside |