Oxidative bond formation and reductive bond cleavage at main group metal centers: reactivity of five-valence-electron MX₂ radicals.
Monomeric five-valence-electron bis(boryl) complexes of gallium, indium, and thallium undergo oxidative M-C bond formation with 2,3-dimethylbutadiene, in a manner consistent with both the redox properties expected for M(II) species and with metal-centered radical character. The weaker nature of the...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2014
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| _version_ | 1797088428251152384 |
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| author | Protchenko, A Dange, D Blake, M Schwarz, A Jones, C Mountford, P Aldridge, S |
| author_facet | Protchenko, A Dange, D Blake, M Schwarz, A Jones, C Mountford, P Aldridge, S |
| author_sort | Protchenko, A |
| collection | OXFORD |
| description | Monomeric five-valence-electron bis(boryl) complexes of gallium, indium, and thallium undergo oxidative M-C bond formation with 2,3-dimethylbutadiene, in a manner consistent with both the redox properties expected for M(II) species and with metal-centered radical character. The weaker nature of the M-C bond for the heavier two elements leads to the observation of reversibility in M-C bond formation (for indium) and to the isolation of products resulting from subsequent B-C reductive elimination (for both indium and thallium). |
| first_indexed | 2024-03-07T02:49:56Z |
| format | Journal article |
| id | oxford-uuid:ad58793b-e072-432f-9615-9e720ea118a8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:49:56Z |
| publishDate | 2014 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:ad58793b-e072-432f-9615-9e720ea118a82022-03-27T03:34:58ZOxidative bond formation and reductive bond cleavage at main group metal centers: reactivity of five-valence-electron MX₂ radicals.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ad58793b-e072-432f-9615-9e720ea118a8EnglishSymplectic Elements at OxfordAmerican Chemical Society2014Protchenko, ADange, DBlake, MSchwarz, AJones, CMountford, PAldridge, SMonomeric five-valence-electron bis(boryl) complexes of gallium, indium, and thallium undergo oxidative M-C bond formation with 2,3-dimethylbutadiene, in a manner consistent with both the redox properties expected for M(II) species and with metal-centered radical character. The weaker nature of the M-C bond for the heavier two elements leads to the observation of reversibility in M-C bond formation (for indium) and to the isolation of products resulting from subsequent B-C reductive elimination (for both indium and thallium). |
| spellingShingle | Protchenko, A Dange, D Blake, M Schwarz, A Jones, C Mountford, P Aldridge, S Oxidative bond formation and reductive bond cleavage at main group metal centers: reactivity of five-valence-electron MX₂ radicals. |
| title | Oxidative bond formation and reductive bond cleavage at main group metal centers: reactivity of five-valence-electron MX₂ radicals. |
| title_full | Oxidative bond formation and reductive bond cleavage at main group metal centers: reactivity of five-valence-electron MX₂ radicals. |
| title_fullStr | Oxidative bond formation and reductive bond cleavage at main group metal centers: reactivity of five-valence-electron MX₂ radicals. |
| title_full_unstemmed | Oxidative bond formation and reductive bond cleavage at main group metal centers: reactivity of five-valence-electron MX₂ radicals. |
| title_short | Oxidative bond formation and reductive bond cleavage at main group metal centers: reactivity of five-valence-electron MX₂ radicals. |
| title_sort | oxidative bond formation and reductive bond cleavage at main group metal centers reactivity of five valence electron mx₂ radicals |
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