Unexpected interactions between alkyl straps and pyridine ligands in sulfur-strapped porphyrin nanorings
Strapped or "basket-handle" porphyrins have been investigated previously as hemoglobin mimics and catalysts. The facial selectivity of their interactions with axial ligands is a sensitive test for noncovalent bonding. Here the binding of pyridyl ligands to zinc porphyrins with thioester-li...
Hauptverfasser: | , , , , , , , |
---|---|
Format: | Journal article |
Sprache: | English |
Veröffentlicht: |
American Chemical Society
2017
|