Unexpected interactions between alkyl straps and pyridine ligands in sulfur-strapped porphyrin nanorings

Strapped or "basket-handle" porphyrins have been investigated previously as hemoglobin mimics and catalysts. The facial selectivity of their interactions with axial ligands is a sensitive test for noncovalent bonding. Here the binding of pyridyl ligands to zinc porphyrins with thioester-li...

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Autori principali: Roche, C, Luo, Q, Gil-Ramírez, G, Jiang, H, Kohn, D, Xiong, Y, Thompson, A, Anderson, H
Natura: Journal article
Lingua:English
Pubblicazione: American Chemical Society 2017