Synthesis of (+)-obtusenyne.
An enantioselective synthesis of the halogenated medium-ring ether natural product (+)-obtusenyne is reported which uses the ring expansion of a seven-membered ketene acetal by means of a Claisen rearrangement to construct the core nine-membered oxygen heterocycle. The trans substituents across the...
Main Authors: | Mak, S, Curtis, N, Payne, A, Congreve, MS, Wildsmith, A, Francis, C, Davies, J, Pascu, S, Burton, J, Holmes, AB |
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Format: | Journal article |
Language: | English |
Published: |
2008
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