Synthesis of conjugated polyrotaxanes.

Synthesis of conjugated polyrotaxanes.

A series of conjugated polyrotaxane insulated molecular wires are synthesised by aqueous Suzuki polymerisation, using hydrophobic binding to promote threading of the cyclodextrin units. These polyrotaxanes have conjugated polymer cores based on poly(para-phenylene), polyfluorene, and poly(diphenylen...

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Príomhchruthaitheoirí:	Michels, J, O'Connell, M, Taylor, P, Wilson, J, Cacialli, F, Anderson, H
Formáid:	Journal article
Teanga:	English
Foilsithe / Cruthaithe:	2003

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Insulated Molecular Wires: Synthesis of Conjugated Polyrotaxanes by Suzuki Coupling in Water We are grateful to Carol A. Stanier for valuable discussion and to Professor Christopher J. Schofield for providing facilities for gel electrophoresis. Disodium 1-aminonaphthalene-3,6-disulfonate was generously provided by Dr. M. G. Hutchings of BASF plc (Cheadle Hulme, UK). This project is funded by the Engineering and Physical Sciences Research Council (UK).
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