Anion sensing in aqueous media by photo-active transition-metal bipyridyl rotaxanes.
A chloride anion templation methodology is utilized in the construction of novel transition-metal rhenium(I) and ruthenium(II) bipyridyl appended [2]rotaxanes. (1)H NMR spectroscopic titrations reveal the ability of the rotaxanes to selectively bind chloride over the more basic oxoanions, with the r...
| Main Authors: | , , , |
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| 格式: | Journal article |
| 語言: | English |
| 出版: |
2012
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