Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment.
The reaction of (eta(5)-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield.
| Główni autorzy: | , , , , , , , |
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| Format: | Journal article |
| Język: | English |
| Wydane: |
2006
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| _version_ | 1826290959699148800 |
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| author | Aldridge, S Kays, D Al-Fawaz, A Jones, K Horton, P Hursthouse, M Harrington, R Clegg, W |
| author_facet | Aldridge, S Kays, D Al-Fawaz, A Jones, K Horton, P Hursthouse, M Harrington, R Clegg, W |
| author_sort | Aldridge, S |
| collection | OXFORD |
| description | The reaction of (eta(5)-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield. |
| first_indexed | 2024-03-07T02:52:10Z |
| format | Journal article |
| id | oxford-uuid:ae09890f-89dd-41dd-b215-d30b05eae7e8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:52:10Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:ae09890f-89dd-41dd-b215-d30b05eae7e82022-03-27T03:39:58ZMigratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ae09890f-89dd-41dd-b215-d30b05eae7e8EnglishSymplectic Elements at Oxford2006Aldridge, SKays, DAl-Fawaz, AJones, KHorton, PHursthouse, MHarrington, RClegg, WThe reaction of (eta(5)-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield. |
| spellingShingle | Aldridge, S Kays, D Al-Fawaz, A Jones, K Horton, P Hursthouse, M Harrington, R Clegg, W Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment. |
| title | Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment. |
| title_full | Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment. |
| title_fullStr | Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment. |
| title_full_unstemmed | Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment. |
| title_short | Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment. |
| title_sort | migratory insertion of b c6f5 2 into c h bonds co promoted transfer of the boryl fragment |
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