Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment.
The reaction of (eta(5)-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield.
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Journal article |
| Jezik: | English |
| Izdano: |
2006
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