Synthesis of novel molybdaboranes from (eta(5)-C5R5)MoCln precursors (R=H,Me; n=1,2,4)
Reaction of Cp*MoCl4(1), or (Cp*MoCl2)2 (2), Cp* = η5-C5Me5, with BH3·THF ultimately generates the Mo(II) cluster (Cp*Mo)2B5H9 (7), together with the Mo(III) species (Cp*MoCl)2B4H10, 4. Prereduction of 2 before reaction with BH3·THF yields only 7. The structure of 4 consists of two Cp*Mo units bridg...
| Autors principals: | , , |
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| Format: | Journal article |
| Idioma: | English |
| Publicat: |
American Chemical Society
1998
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