pH-dependent conformational switching in 2,6-benzamidodiphenylacetylenes.
The conformational equilibrium of a pH-dependent switch based on an intramolecularly H-bonded diphenylacetylene can be predictably biased by using electron-donating or -withdrawing groups. Furthermore, protonation of the electron-donating dimethylamino group converts it into an electron-withdrawing...
Main Authors: | Jones, I, Lingard, H, Hamilton, A |
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Format: | Journal article |
Language: | English |
Published: |
2011
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