Synthesis, structure and reactivity of stable homoleptic gold(i) alkene cations.
Stable gold(I) cations: Treatment of [AuCI(SMe 2)] with AgSbF 6 in CH 2CI 2 at room temperature in the presence of norbornene leads smoothly to the formation of a complex containing the homoleptic tris (...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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2009
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| _version_ | 1797089089482129408 |
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| author | Hooper, T Butts, C Green, M Haddow, M McGrady, J Russell, C |
| author_facet | Hooper, T Butts, C Green, M Haddow, M McGrady, J Russell, C |
| author_sort | Hooper, T |
| collection | OXFORD |
| description | Stable gold(I) cations: Treatment of [AuCI(SMe 2)] with AgSbF 6 in CH 2CI 2 at room temperature in the presence of norbornene leads smoothly to the formation of a complex containing the homoleptic tris (eta; 2-norbornene)gold(I) cation (see figure). The complex shows appreciable stability in the solid state and may be stabilised in solution by the addition of excess norbornene. © 2009 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-07T02:59:28Z |
| format | Journal article |
| id | oxford-uuid:b0773141-da41-46cf-9888-9512008c37ff |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:59:28Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:b0773141-da41-46cf-9888-9512008c37ff2022-03-27T03:56:39ZSynthesis, structure and reactivity of stable homoleptic gold(i) alkene cations.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b0773141-da41-46cf-9888-9512008c37ffEnglishSymplectic Elements at Oxford2009Hooper, TButts, CGreen, MHaddow, MMcGrady, JRussell, CStable gold(I) cations: Treatment of [AuCI(SMe 2)] with AgSbF 6 in CH 2CI 2 at room temperature in the presence of norbornene leads smoothly to the formation of a complex containing the homoleptic tris (eta; 2-norbornene)gold(I) cation (see figure). The complex shows appreciable stability in the solid state and may be stabilised in solution by the addition of excess norbornene. © 2009 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Hooper, T Butts, C Green, M Haddow, M McGrady, J Russell, C Synthesis, structure and reactivity of stable homoleptic gold(i) alkene cations. |
| title | Synthesis, structure and reactivity of stable homoleptic gold(i) alkene cations. |
| title_full | Synthesis, structure and reactivity of stable homoleptic gold(i) alkene cations. |
| title_fullStr | Synthesis, structure and reactivity of stable homoleptic gold(i) alkene cations. |
| title_full_unstemmed | Synthesis, structure and reactivity of stable homoleptic gold(i) alkene cations. |
| title_short | Synthesis, structure and reactivity of stable homoleptic gold(i) alkene cations. |
| title_sort | synthesis structure and reactivity of stable homoleptic gold i alkene cations |
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