Spectroscopic investigations of bis(sulfoximine) copper(II) complexes and their relevance in asymmetric catalysis.
The structure of Cu(II) complex 3 formed within the course of a stereoselective Diels-Alder reaction was investigated by EXAFS, CW-EPR at X- and W-band, HYSCORE, pulsed ENDOR, and UV-vis spectroscopy. The experimental techniques indicate that the chiral bis(sulfoximine) ligand (S,S)-1 and the dienop...
Main Authors: | Bolm, C, Martin, M, Gescheidt, G, Palivan, C, Neshchadin, D, Bertagnolli, H, Feth, M, Schweiger, A, Mitrikas, G, Harmer, J |
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Format: | Journal article |
Language: | English |
Published: |
2003
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