Bimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic Properties
A series of bimetallic lanthanide complexes was prepared from a bimacrocyclic system in which two DO3A units are linked by a m-xylyl unit appended with either a NO2 or an NH2 group (DO3A=1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). The Nd-, Eu-, Tb- and Yb-complexes were all luminescent: ti...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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2009
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| _version_ | 1826291693994901504 |
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| author | Placidi, M Natrajan, L Sykes, D Kenwright, A Faulkner, S |
| author_facet | Placidi, M Natrajan, L Sykes, D Kenwright, A Faulkner, S |
| author_sort | Placidi, M |
| collection | OXFORD |
| description | A series of bimetallic lanthanide complexes was prepared from a bimacrocyclic system in which two DO3A units are linked by a m-xylyl unit appended with either a NO2 or an NH2 group (DO3A=1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). The Nd-, Eu-, Tb- and Yb-complexes were all luminescent: time-resolved studies indicated that the lipophilic xylyl group restricts close approach of H2O to the metal centre. © 2009 Verlag Helvetica Chimica Acta AG. |
| first_indexed | 2024-03-07T03:03:16Z |
| format | Journal article |
| id | oxford-uuid:b1a8d977-a20c-48cd-9d3b-3972eefd8027 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:03:16Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:b1a8d977-a20c-48cd-9d3b-3972eefd80272022-03-27T04:05:47ZBimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic PropertiesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b1a8d977-a20c-48cd-9d3b-3972eefd8027EnglishSymplectic Elements at Oxford2009Placidi, MNatrajan, LSykes, DKenwright, AFaulkner, SA series of bimetallic lanthanide complexes was prepared from a bimacrocyclic system in which two DO3A units are linked by a m-xylyl unit appended with either a NO2 or an NH2 group (DO3A=1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). The Nd-, Eu-, Tb- and Yb-complexes were all luminescent: time-resolved studies indicated that the lipophilic xylyl group restricts close approach of H2O to the metal centre. © 2009 Verlag Helvetica Chimica Acta AG. |
| spellingShingle | Placidi, M Natrajan, L Sykes, D Kenwright, A Faulkner, S Bimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic Properties |
| title | Bimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic Properties |
| title_full | Bimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic Properties |
| title_fullStr | Bimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic Properties |
| title_full_unstemmed | Bimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic Properties |
| title_short | Bimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic Properties |
| title_sort | bimetallic lanthanide complexes derived from macrocycle appended m xylyl derivatives synthesis and spectroscopic properties |
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