Amino-borane oligomers bound to a Rh(I) metal fragment.
Coordination complexes of previously observed intermediates, H(3)B.NMe(2)BH(2).NMe(2)H and [H(2)BNMeH](3), in the transition metal catalysed dehydrocoupling of H(3)B.NMe(2)H and H(3)B.NMeH(2) have been isolated and structurally characterised using the [Rh{PR'(2)(eta(2)-C(5)H(7))}](+) fragment....
| Main Authors: | , , , |
|---|---|
| 格式: | Journal article |
| 語言: | English |
| 出版: |
2010
|
| 總結: | Coordination complexes of previously observed intermediates, H(3)B.NMe(2)BH(2).NMe(2)H and [H(2)BNMeH](3), in the transition metal catalysed dehydrocoupling of H(3)B.NMe(2)H and H(3)B.NMeH(2) have been isolated and structurally characterised using the [Rh{PR'(2)(eta(2)-C(5)H(7))}](+) fragment. Their onward reactivity shows that further dehydrogenation is not a simple intramolecular process. |
|---|