Amino-borane oligomers bound to a Rh(I) metal fragment.
Coordination complexes of previously observed intermediates, H(3)B.NMe(2)BH(2).NMe(2)H and [H(2)BNMeH](3), in the transition metal catalysed dehydrocoupling of H(3)B.NMe(2)H and H(3)B.NMeH(2) have been isolated and structurally characterised using the [Rh{PR'(2)(eta(2)-C(5)H(7))}](+) fragment....
Main Authors: | Dallanegra, R, Chaplin, AB, Tsim, J, Weller, A |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2010
|
Similar Items
-
Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes.
by: Chaplin, AB, et al.
Published: (2010) -
Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment.
by: Dallanegra, R, et al.
Published: (2011) -
Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center.
by: Dallanegra, R, et al.
Published: (2009) -
Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation.
by: Sewell, L, et al.
Published: (2011) -
Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes.
by: Douglas, T, et al.
Published: (2008)