3-O-tert-butyldimethylsilyl-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxymethyl-D-1,4-gluconolactone
The C19H34O7Si was derived from the minor component of a Kiliani reaction on d-fructose. Its crystal structure has been determined in order to confirm its structure, and stereochemistry. The scaffolds provide efficient access to highly functionalized compounds containing non-linear carbon chains. Th...
| Hlavní autoři: | , , , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
2004
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| Shrnutí: | The C19H34O7Si was derived from the minor component of a Kiliani reaction on d-fructose. Its crystal structure has been determined in order to confirm its structure, and stereochemistry. The scaffolds provide efficient access to highly functionalized compounds containing non-linear carbon chains. The Kiliani reaction of d-fructose proceeds in good yield to give a mixture of the two diastereomers which cannot easily be separated. The direct treatment of the crude material produced the diacetonide as the major product, which crystallized easily. |
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