3-O-tert-butyldimethylsilyl-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxymethyl-D-1,4-gluconolactone
The C19H34O7Si was derived from the minor component of a Kiliani reaction on d-fructose. Its crystal structure has been determined in order to confirm its structure, and stereochemistry. The scaffolds provide efficient access to highly functionalized compounds containing non-linear carbon chains. Th...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2004
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| _version_ | 1797089483754045440 |
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| author | Cowley, A Fleet, G Simone, M Soengas, R |
| author_facet | Cowley, A Fleet, G Simone, M Soengas, R |
| author_sort | Cowley, A |
| collection | OXFORD |
| description | The C19H34O7Si was derived from the minor component of a Kiliani reaction on d-fructose. Its crystal structure has been determined in order to confirm its structure, and stereochemistry. The scaffolds provide efficient access to highly functionalized compounds containing non-linear carbon chains. The Kiliani reaction of d-fructose proceeds in good yield to give a mixture of the two diastereomers which cannot easily be separated. The direct treatment of the crude material produced the diacetonide as the major product, which crystallized easily. |
| first_indexed | 2024-03-07T03:04:44Z |
| format | Journal article |
| id | oxford-uuid:b21d5c25-26ab-4f3c-a0b1-94851cd1f30a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:04:44Z |
| publishDate | 2004 |
| record_format | dspace |
| spelling | oxford-uuid:b21d5c25-26ab-4f3c-a0b1-94851cd1f30a2022-03-27T04:09:24Z3-O-tert-butyldimethylsilyl-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxymethyl-D-1,4-gluconolactoneJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b21d5c25-26ab-4f3c-a0b1-94851cd1f30aEnglishSymplectic Elements at Oxford2004Cowley, AFleet, GSimone, MSoengas, RThe C19H34O7Si was derived from the minor component of a Kiliani reaction on d-fructose. Its crystal structure has been determined in order to confirm its structure, and stereochemistry. The scaffolds provide efficient access to highly functionalized compounds containing non-linear carbon chains. The Kiliani reaction of d-fructose proceeds in good yield to give a mixture of the two diastereomers which cannot easily be separated. The direct treatment of the crude material produced the diacetonide as the major product, which crystallized easily. |
| spellingShingle | Cowley, A Fleet, G Simone, M Soengas, R 3-O-tert-butyldimethylsilyl-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxymethyl-D-1,4-gluconolactone |
| title | 3-O-tert-butyldimethylsilyl-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxymethyl-D-1,4-gluconolactone |
| title_full | 3-O-tert-butyldimethylsilyl-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxymethyl-D-1,4-gluconolactone |
| title_fullStr | 3-O-tert-butyldimethylsilyl-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxymethyl-D-1,4-gluconolactone |
| title_full_unstemmed | 3-O-tert-butyldimethylsilyl-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxymethyl-D-1,4-gluconolactone |
| title_short | 3-O-tert-butyldimethylsilyl-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxymethyl-D-1,4-gluconolactone |
| title_sort | 3 o tert butyldimethylsilyl 2 2 5 6 di o isopropylidene 2 c hydroxymethyl d 1 4 gluconolactone |
| work_keys_str_mv | AT cowleya 3otertbutyldimethylsilyl2256dioisopropylidene2chydroxymethyld14gluconolactone AT fleetg 3otertbutyldimethylsilyl2256dioisopropylidene2chydroxymethyld14gluconolactone AT simonem 3otertbutyldimethylsilyl2256dioisopropylidene2chydroxymethyld14gluconolactone AT soengasr 3otertbutyldimethylsilyl2256dioisopropylidene2chydroxymethyld14gluconolactone |