Roaming is the dominant mechanism for molecular products in acetaldehyde photodissociation.

Roaming is the dominant mechanism for molecular products in acetaldehyde photodissociation.

Reaction pathways that bypass the conventional saddle-point transition state (TS) are of considerable interest and importance. An example of such a pathway, termed "roaming," has been described in the photodissociation of H(2)CO. In a combined experimental and theoretical study, we show th...

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Bibliografiske detaljer
Main Authors:	Heazlewood, B, Jordan, M, Kable, S, Selby, T, Osborn, D, Shepler, B, Braams, B, Bowman, J
Format:	Journal article
Sprog:	English
Udgivet:	2008

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