Chemical functionalization of polyethylene surfaces by plasma-assisted carbene insertion
Controlled surface modification of PE is achieved by an efficient and facile approach via plasma-assisted carbene insertion generated using diazo chemistry. The combination of plasma and carbene insertion shows a synergistic effect, which leads to an obvious enhancement of surface grafting, as shown...
Main Authors: | , , , , |
---|---|
Format: | Journal article |
Published: |
Taylor and Francis
2017
|
_version_ | 1797089859297345536 |
---|---|
author | Hu, Z Moloney, M Parker, E Chng, S Wu, L |
author_facet | Hu, Z Moloney, M Parker, E Chng, S Wu, L |
author_sort | Hu, Z |
collection | OXFORD |
description | Controlled surface modification of PE is achieved by an efficient and facile approach via plasma-assisted carbene insertion generated using diazo chemistry. The combination of plasma and carbene insertion shows a synergistic effect, which leads to an obvious enhancement of surface grafting, as shown qualitatively by a combination of IR and UV reflectance spectroscopy, and XPS analysis. The chemical modification may be observed spectroscopically, and the approach provides an opportunity for the convenient modification of low surface energy materials. |
first_indexed | 2024-03-07T03:10:09Z |
format | Journal article |
id | oxford-uuid:b3ea469d-ca9c-4fc8-8775-157b2279ffae |
institution | University of Oxford |
last_indexed | 2024-03-07T03:10:09Z |
publishDate | 2017 |
publisher | Taylor and Francis |
record_format | dspace |
spelling | oxford-uuid:b3ea469d-ca9c-4fc8-8775-157b2279ffae2022-03-27T04:22:30ZChemical functionalization of polyethylene surfaces by plasma-assisted carbene insertionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b3ea469d-ca9c-4fc8-8775-157b2279ffaeSymplectic Elements at OxfordTaylor and Francis2017Hu, ZMoloney, MParker, EChng, SWu, LControlled surface modification of PE is achieved by an efficient and facile approach via plasma-assisted carbene insertion generated using diazo chemistry. The combination of plasma and carbene insertion shows a synergistic effect, which leads to an obvious enhancement of surface grafting, as shown qualitatively by a combination of IR and UV reflectance spectroscopy, and XPS analysis. The chemical modification may be observed spectroscopically, and the approach provides an opportunity for the convenient modification of low surface energy materials. |
spellingShingle | Hu, Z Moloney, M Parker, E Chng, S Wu, L Chemical functionalization of polyethylene surfaces by plasma-assisted carbene insertion |
title | Chemical functionalization of polyethylene surfaces by plasma-assisted carbene insertion |
title_full | Chemical functionalization of polyethylene surfaces by plasma-assisted carbene insertion |
title_fullStr | Chemical functionalization of polyethylene surfaces by plasma-assisted carbene insertion |
title_full_unstemmed | Chemical functionalization of polyethylene surfaces by plasma-assisted carbene insertion |
title_short | Chemical functionalization of polyethylene surfaces by plasma-assisted carbene insertion |
title_sort | chemical functionalization of polyethylene surfaces by plasma assisted carbene insertion |
work_keys_str_mv | AT huz chemicalfunctionalizationofpolyethylenesurfacesbyplasmaassistedcarbeneinsertion AT moloneym chemicalfunctionalizationofpolyethylenesurfacesbyplasmaassistedcarbeneinsertion AT parkere chemicalfunctionalizationofpolyethylenesurfacesbyplasmaassistedcarbeneinsertion AT chngs chemicalfunctionalizationofpolyethylenesurfacesbyplasmaassistedcarbeneinsertion AT wul chemicalfunctionalizationofpolyethylenesurfacesbyplasmaassistedcarbeneinsertion |