Anion-templated assembly of interpenetrated and interlocked structures.
The rational development of a general anion templation strategy for the construction of a variety of interpenetrated and interlocked molecular structures based upon the coupling of anion recognition with ion-pairing is described. The success of this anion templation methodology is demonstrated with...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2006
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| _version_ | 1797089883665203200 |
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| author | Beer, P Sambrook, MR Curiel, D |
| author_facet | Beer, P Sambrook, MR Curiel, D |
| author_sort | Beer, P |
| collection | OXFORD |
| description | The rational development of a general anion templation strategy for the construction of a variety of interpenetrated and interlocked molecular structures based upon the coupling of anion recognition with ion-pairing is described. The success of this anion templation methodology is demonstrated with the halide anion directed assembly of a series of novel [2]pseudorotaxanes containing pyridinium, pyridinium nicotinamide, imidazolium, benzimidazolium and guanidinium threading components and anion binding macrocyclic ligands. Interlocked [2]rotaxane and [2]catenane molecular structures are also synthesised using this anion templation protocol. These interlocked structures feature unique topologically defined hydrogen bond donating binding domains that exhibit a high degree of selectivity for chloride, the templating anion. A series of rhenium(I) bipyridyl containing [2]pseudorotaxane assemblies and a [2]rotaxane further highlight the potential this strategic anion templation approach has in future chemical sensor design and fabrication. |
| first_indexed | 2024-03-07T03:10:25Z |
| format | Journal article |
| id | oxford-uuid:b404512c-173a-4001-8949-770429248e6a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:10:25Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:b404512c-173a-4001-8949-770429248e6a2022-03-27T04:23:09ZAnion-templated assembly of interpenetrated and interlocked structures.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b404512c-173a-4001-8949-770429248e6aEnglishSymplectic Elements at Oxford2006Beer, PSambrook, MRCuriel, DThe rational development of a general anion templation strategy for the construction of a variety of interpenetrated and interlocked molecular structures based upon the coupling of anion recognition with ion-pairing is described. The success of this anion templation methodology is demonstrated with the halide anion directed assembly of a series of novel [2]pseudorotaxanes containing pyridinium, pyridinium nicotinamide, imidazolium, benzimidazolium and guanidinium threading components and anion binding macrocyclic ligands. Interlocked [2]rotaxane and [2]catenane molecular structures are also synthesised using this anion templation protocol. These interlocked structures feature unique topologically defined hydrogen bond donating binding domains that exhibit a high degree of selectivity for chloride, the templating anion. A series of rhenium(I) bipyridyl containing [2]pseudorotaxane assemblies and a [2]rotaxane further highlight the potential this strategic anion templation approach has in future chemical sensor design and fabrication. |
| spellingShingle | Beer, P Sambrook, MR Curiel, D Anion-templated assembly of interpenetrated and interlocked structures. |
| title | Anion-templated assembly of interpenetrated and interlocked structures. |
| title_full | Anion-templated assembly of interpenetrated and interlocked structures. |
| title_fullStr | Anion-templated assembly of interpenetrated and interlocked structures. |
| title_full_unstemmed | Anion-templated assembly of interpenetrated and interlocked structures. |
| title_short | Anion-templated assembly of interpenetrated and interlocked structures. |
| title_sort | anion templated assembly of interpenetrated and interlocked structures |
| work_keys_str_mv | AT beerp aniontemplatedassemblyofinterpenetratedandinterlockedstructures AT sambrookmr aniontemplatedassemblyofinterpenetratedandinterlockedstructures AT curield aniontemplatedassemblyofinterpenetratedandinterlockedstructures |