A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride.
A ferrocene appended rotaxane is prepared by chloride anion templation and ring closing metathesis. Upon removal of the chloride template, the rotaxane is demonstrated to be selective for chloride over more basic oxoanions by (1)H NMR spectroscopy and electrochemistry, in marked contrast to an acycl...
| Hauptverfasser: | , |
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| Format: | Journal article |
| Sprache: | English |
| Veröffentlicht: |
2011
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| _version_ | 1826292212136148992 |
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| author | Evans, N Beer, P |
| author_facet | Evans, N Beer, P |
| author_sort | Evans, N |
| collection | OXFORD |
| description | A ferrocene appended rotaxane is prepared by chloride anion templation and ring closing metathesis. Upon removal of the chloride template, the rotaxane is demonstrated to be selective for chloride over more basic oxoanions by (1)H NMR spectroscopy and electrochemistry, in marked contrast to an acyclic analogue--the first example of a solution based redox-active interlocked host system capable of the electrochemical recognition of anions. |
| first_indexed | 2024-03-07T03:11:12Z |
| format | Journal article |
| id | oxford-uuid:b442f9c5-a46b-47d3-8b70-810d5ea6a4d2 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:11:12Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:b442f9c5-a46b-47d3-8b70-810d5ea6a4d22022-03-27T04:24:47ZA ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b442f9c5-a46b-47d3-8b70-810d5ea6a4d2EnglishSymplectic Elements at Oxford2011Evans, NBeer, PA ferrocene appended rotaxane is prepared by chloride anion templation and ring closing metathesis. Upon removal of the chloride template, the rotaxane is demonstrated to be selective for chloride over more basic oxoanions by (1)H NMR spectroscopy and electrochemistry, in marked contrast to an acyclic analogue--the first example of a solution based redox-active interlocked host system capable of the electrochemical recognition of anions. |
| spellingShingle | Evans, N Beer, P A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride. |
| title | A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride. |
| title_full | A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride. |
| title_fullStr | A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride. |
| title_full_unstemmed | A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride. |
| title_short | A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride. |
| title_sort | ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride |
| work_keys_str_mv | AT evansn aferrocenefunctionalizedrotaxanehostsystemcapableoftheelectrochemicalrecognitionofchloride AT beerp aferrocenefunctionalizedrotaxanehostsystemcapableoftheelectrochemicalrecognitionofchloride AT evansn ferrocenefunctionalizedrotaxanehostsystemcapableoftheelectrochemicalrecognitionofchloride AT beerp ferrocenefunctionalizedrotaxanehostsystemcapableoftheelectrochemicalrecognitionofchloride |