Intermolecular alkene and alkyne hydroacylation with beta-S-substituted aldehydes: mechanistic insight into the role of a hemilabile P-O-P ligand.
A straightforward to assemble catalytic system for the intermolecular hydroacylation reaction of beta-S-substituted aldehydes with activated and unactivated alkenes and alkynes is reported. These catalysts promote the hydroacylation reaction between beta-S-substituted aldehydes and challenging subst...
Main Authors: | Moxham, G, Randell-Sly, H, Brayshaw, S, Weller, A, Willis, M |
---|---|
פורמט: | Journal article |
שפה: | English |
יצא לאור: |
2008
|
פריטים דומים
-
A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand.
מאת: Moxham, G, et al.
יצא לאור: (2006) -
Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.
מאת: Willis, M, et al.
יצא לאור: (2005) -
Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
מאת: Willis, M, et al.
יצא לאור: (2006) -
Controlling Selectivity in Intermolecular Alkene or Aldehyde Hydroacylation Reactions Catalyzed by {Rh(L-2)}(+) Fragments
מאת: Pawley, R, et al.
יצא לאור: (2010) -
Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
מאת: Hooper, J, et al.
יצא לאור: (2013)