Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals
Herein, we report the synthesis of three covalently linked superparamagnetic nanocrystal-multi-walled carbon nanotube (MWCNT) composites. A generic strategy for amphiphilic polymer coating of nanocrystals and further functionalization for amide bond formation with the MWCNTs is discussed. This appro...
Main Authors: | , , , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2012
|
_version_ | 1826292365362462720 |
---|---|
author | Bear, J McNaughter, P Jurkschat, K Crossley, A Aldous, L Compton, R Mayes, A Wildgoose, G |
author_facet | Bear, J McNaughter, P Jurkschat, K Crossley, A Aldous, L Compton, R Mayes, A Wildgoose, G |
author_sort | Bear, J |
collection | OXFORD |
description | Herein, we report the synthesis of three covalently linked superparamagnetic nanocrystal-multi-walled carbon nanotube (MWCNT) composites. A generic strategy for amphiphilic polymer coating of nanocrystals and further functionalization for amide bond formation with the MWCNTs is discussed. This approach can in principle allow attachment of any colloidal nanocrystal to the MWCNTs. The materials were characterized at each stage of the syntheses using DLS, zeta-potential measurements, FT-IR, TEM, and XPS techniques. The practicality of this linkage is demonstrated by the reversible magnetic immobilization of these materials on an electrode during non-aqueous electrochemistry. © 2012 Elsevier Inc. |
first_indexed | 2024-03-07T03:13:34Z |
format | Journal article |
id | oxford-uuid:b509bf47-e7b0-4ffc-a818-0b7c3ca8c7d2 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T03:13:34Z |
publishDate | 2012 |
record_format | dspace |
spelling | oxford-uuid:b509bf47-e7b0-4ffc-a818-0b7c3ca8c7d22022-03-27T04:30:22ZSynthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystalsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b509bf47-e7b0-4ffc-a818-0b7c3ca8c7d2EnglishSymplectic Elements at Oxford2012Bear, JMcNaughter, PJurkschat, KCrossley, AAldous, LCompton, RMayes, AWildgoose, GHerein, we report the synthesis of three covalently linked superparamagnetic nanocrystal-multi-walled carbon nanotube (MWCNT) composites. A generic strategy for amphiphilic polymer coating of nanocrystals and further functionalization for amide bond formation with the MWCNTs is discussed. This approach can in principle allow attachment of any colloidal nanocrystal to the MWCNTs. The materials were characterized at each stage of the syntheses using DLS, zeta-potential measurements, FT-IR, TEM, and XPS techniques. The practicality of this linkage is demonstrated by the reversible magnetic immobilization of these materials on an electrode during non-aqueous electrochemistry. © 2012 Elsevier Inc. |
spellingShingle | Bear, J McNaughter, P Jurkschat, K Crossley, A Aldous, L Compton, R Mayes, A Wildgoose, G Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals |
title | Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals |
title_full | Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals |
title_fullStr | Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals |
title_full_unstemmed | Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals |
title_short | Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals |
title_sort | synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals |
work_keys_str_mv | AT bearj synthesisandcharacterizationofcarbonnanotubescovalentlyfunctionalizedwithamphiphilicpolymercoatedsuperparamagneticnanocrystals AT mcnaughterp synthesisandcharacterizationofcarbonnanotubescovalentlyfunctionalizedwithamphiphilicpolymercoatedsuperparamagneticnanocrystals AT jurkschatk synthesisandcharacterizationofcarbonnanotubescovalentlyfunctionalizedwithamphiphilicpolymercoatedsuperparamagneticnanocrystals AT crossleya synthesisandcharacterizationofcarbonnanotubescovalentlyfunctionalizedwithamphiphilicpolymercoatedsuperparamagneticnanocrystals AT aldousl synthesisandcharacterizationofcarbonnanotubescovalentlyfunctionalizedwithamphiphilicpolymercoatedsuperparamagneticnanocrystals AT comptonr synthesisandcharacterizationofcarbonnanotubescovalentlyfunctionalizedwithamphiphilicpolymercoatedsuperparamagneticnanocrystals AT mayesa synthesisandcharacterizationofcarbonnanotubescovalentlyfunctionalizedwithamphiphilicpolymercoatedsuperparamagneticnanocrystals AT wildgooseg synthesisandcharacterizationofcarbonnanotubescovalentlyfunctionalizedwithamphiphilicpolymercoatedsuperparamagneticnanocrystals |