Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals

Herein, we report the synthesis of three covalently linked superparamagnetic nanocrystal-multi-walled carbon nanotube (MWCNT) composites. A generic strategy for amphiphilic polymer coating of nanocrystals and further functionalization for amide bond formation with the MWCNTs is discussed. This appro...

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Main Authors: Bear, J, McNaughter, P, Jurkschat, K, Crossley, A, Aldous, L, Compton, R, Mayes, A, Wildgoose, G
Format: Journal article
Language:English
Published: 2012
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author Bear, J
McNaughter, P
Jurkschat, K
Crossley, A
Aldous, L
Compton, R
Mayes, A
Wildgoose, G
author_facet Bear, J
McNaughter, P
Jurkschat, K
Crossley, A
Aldous, L
Compton, R
Mayes, A
Wildgoose, G
author_sort Bear, J
collection OXFORD
description Herein, we report the synthesis of three covalently linked superparamagnetic nanocrystal-multi-walled carbon nanotube (MWCNT) composites. A generic strategy for amphiphilic polymer coating of nanocrystals and further functionalization for amide bond formation with the MWCNTs is discussed. This approach can in principle allow attachment of any colloidal nanocrystal to the MWCNTs. The materials were characterized at each stage of the syntheses using DLS, zeta-potential measurements, FT-IR, TEM, and XPS techniques. The practicality of this linkage is demonstrated by the reversible magnetic immobilization of these materials on an electrode during non-aqueous electrochemistry. © 2012 Elsevier Inc.
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spelling oxford-uuid:b509bf47-e7b0-4ffc-a818-0b7c3ca8c7d22022-03-27T04:30:22ZSynthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystalsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b509bf47-e7b0-4ffc-a818-0b7c3ca8c7d2EnglishSymplectic Elements at Oxford2012Bear, JMcNaughter, PJurkschat, KCrossley, AAldous, LCompton, RMayes, AWildgoose, GHerein, we report the synthesis of three covalently linked superparamagnetic nanocrystal-multi-walled carbon nanotube (MWCNT) composites. A generic strategy for amphiphilic polymer coating of nanocrystals and further functionalization for amide bond formation with the MWCNTs is discussed. This approach can in principle allow attachment of any colloidal nanocrystal to the MWCNTs. The materials were characterized at each stage of the syntheses using DLS, zeta-potential measurements, FT-IR, TEM, and XPS techniques. The practicality of this linkage is demonstrated by the reversible magnetic immobilization of these materials on an electrode during non-aqueous electrochemistry. © 2012 Elsevier Inc.
spellingShingle Bear, J
McNaughter, P
Jurkschat, K
Crossley, A
Aldous, L
Compton, R
Mayes, A
Wildgoose, G
Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals
title Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals
title_full Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals
title_fullStr Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals
title_full_unstemmed Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals
title_short Synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals
title_sort synthesis and characterization of carbon nanotubes covalently functionalized with amphiphilic polymer coated superparamagnetic nanocrystals
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