Asymmetric synthesis of methyl alpha-L-daunosaminide hydrochloride
Methyl α-L-daunosaminide hydrochloride was synthesised in five steps from methyl (E,E)-hexa-2,4-dienoate, via the conjugate addition of (R)-lithium N-benzyl-α-methylbenzylamide, and osmium tetroxide catalysed dihydroxylation of the resulting adduct.
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格式: | Journal article |
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1996
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