An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation

An enamine-controlled hydroacylation of alkynes using a rhodium(I)/dppe catalyst system is described. The reaction is highly selective, forming the linear enaminone products as single regioisomers in all examples. In situ hydrolysis of the enamine functionality generated α-substituted 1,3-diketone p...

Bibliografiset tiedot
Päätekijät:	Straker, R, Formica, M, Lupton, J, Niu, J, Willis, M
Aineistotyyppi:	Journal article
Julkaistu:	Elsevier 2018

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Rhodium (I) catalyzed intermolecular hydroacylation.
Tekijä: Sapmaz, S, et al.
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Tekijä: Randell-Sly, H, et al.
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Tekijä: Parsons, SR, et al.
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Tekijä: Barwick-Silk, J
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Julkaistu: (2012)

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
Tekijä: Osborne, J, et al.
Julkaistu: (2008)

Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
Tekijä: Willis, M, et al.
Julkaistu: (2006)

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Tekijä: Moseley, D
Julkaistu: (2022)

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Tekijä: Willis, M, et al.
Julkaistu: (2016)

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Tekijä: Pernik, I, et al.
Julkaistu: (2012)

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Tekijä: Lenden, P
Julkaistu: (2011)

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.
Tekijä: Chaplin, AB, et al.
Julkaistu: (2012)

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Tekijä: Straker, R, et al.
Julkaistu: (2017)

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
Tekijä: González-Rodríguez, C, et al.
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Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
Tekijä: González-Rodríguez, C, et al.
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Tekijä: Castaing, M, et al.
Julkaistu: (2013)

Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate
Tekijä: Lenden, P, et al.
Julkaistu: (2011)

Rhodium-catalysed linear-selective alkyne hydroacylation.
Tekijä: Poingdestre, S, et al.
Julkaistu: (2012)

Controlling Selectivity in Intermolecular Alkene or Aldehyde Hydroacylation Reactions Catalyzed by {Rh(L-2)}(+) Fragments
Tekijä: Pawley, R, et al.
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Tekijä: Gao, M
Julkaistu: (2018)

Traceless rhodium-catalyzed hydroacylation using alkyl aldehydes: the enantioselective synthesis of β-aryl ketones
Tekijä: Willis, M, et al.
Julkaistu: (2016)

Azine N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
Tekijä: Moseley, DF, et al.
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New applications of rhodium-catalysed hydroacylation
Tekijä: Iwumene, NUN
Julkaistu: (2022)

Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.
Tekijä: Willis, M, et al.
Julkaistu: (2005)

Chelation-controlled intermolecular hydroacylation: direct addition of alkyl aldehydes to functionalized alkenes.
Tekijä: Willis, M, et al.
Julkaistu: (2004)

Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
Tekijä: Majhail, M
Julkaistu: (2016)

New reactivity and selectivity in rhodium-catalysed hydroacylation
Tekijä: Pal, R
Julkaistu: (2020)

Well‐defined and robust rhodium catalysts for the hydroacylation of terminal and internal alkenes
Tekijä: Prades, A, et al.
Julkaistu: (2015)

Transition metal catalyzed alkene and alkyne hydroacylation.
Tekijä: Willis, M
Julkaistu: (2010)

Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.
Tekijä: Osborne, J, et al.
Julkaistu: (2008)

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Tekijä: Willis, M, et al.
Julkaistu: (2001)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
Tekijä: Ylioja, P
Julkaistu: (2011)

Cobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activation
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Julkaistu: (2015)

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Tekijä: Pernik, I
Julkaistu: (2014)

Studies toward the application and development of rhodium-catalysed hydroacylation reactions
Tekijä: Neuhaus, J
Julkaistu: (2016)