An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation

An enamine-controlled hydroacylation of alkynes using a rhodium(I)/dppe catalyst system is described. The reaction is highly selective, forming the linear enaminone products as single regioisomers in all examples. In situ hydrolysis of the enamine functionality generated α-substituted 1,3-diketone p...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Straker, R, Formica, M, Lupton, J, Niu, J, Willis, M
التنسيق: Journal article
منشور في: Elsevier 2018