An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation

An enamine-controlled hydroacylation of alkynes using a rhodium(I)/dppe catalyst system is described. The reaction is highly selective, forming the linear enaminone products as single regioisomers in all examples. In situ hydrolysis of the enamine functionality generated α-substituted 1,3-diketone p...

Volledige beschrijving

Bibliografische gegevens
Hoofdauteurs: Straker, R, Formica, M, Lupton, J, Niu, J, Willis, M
Formaat: Journal article
Gepubliceerd in: Elsevier 2018