Crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ- OGaI(OH)2}]2·3benzene
The crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ-OGaI(OH)2}]2·3benzene has been obtained, revealing the following properties: triclinic, space group P1 with a = 11.191(2), b = 11.468(2), c = 15.913(3)Å, α = 77.18(3), β = 76.65(3), γ = 88.53(3)°, Z = 1, R = 0.030 and wR2 = 0.058 for 7870 ob...
| Main Authors: | , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2007
|
| _version_ | 1797090320166420480 |
|---|---|
| author | Coombs, N Aldridge, S Stasch, A |
| author_facet | Coombs, N Aldridge, S Stasch, A |
| author_sort | Coombs, N |
| collection | OXFORD |
| description | The crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ-OGaI(OH)2}]2·3benzene has been obtained, revealing the following properties: triclinic, space group P1 with a = 11.191(2), b = 11.468(2), c = 15.913(3)Å, α = 77.18(3), β = 76.65(3), γ = 88.53(3)°, Z = 1, R = 0.030 and wR2 = 0.058 for 7870 observed reflections [I > 2σ(I)]. The coordination geometry about the molybdenum-bound gallium centres is approximately tetrahedral with a mean Mo-Ga distance of 2.541 Å and Mo-Ga-O angles of 122.9(1) - 127.7(1)° associated with Ga(1). 2007 © The Japan Society for Analytical Chemistry. |
| first_indexed | 2024-03-07T03:16:51Z |
| format | Journal article |
| id | oxford-uuid:b6121288-dfe2-4ce2-a8c2-9df3d53b2239 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:16:51Z |
| publishDate | 2007 |
| record_format | dspace |
| spelling | oxford-uuid:b6121288-dfe2-4ce2-a8c2-9df3d53b22392022-03-27T04:38:23ZCrystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ- OGaI(OH)2}]2·3benzeneJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b6121288-dfe2-4ce2-a8c2-9df3d53b2239EnglishSymplectic Elements at Oxford2007Coombs, NAldridge, SStasch, AThe crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ-OGaI(OH)2}]2·3benzene has been obtained, revealing the following properties: triclinic, space group P1 with a = 11.191(2), b = 11.468(2), c = 15.913(3)Å, α = 77.18(3), β = 76.65(3), γ = 88.53(3)°, Z = 1, R = 0.030 and wR2 = 0.058 for 7870 observed reflections [I > 2σ(I)]. The coordination geometry about the molybdenum-bound gallium centres is approximately tetrahedral with a mean Mo-Ga distance of 2.541 Å and Mo-Ga-O angles of 122.9(1) - 127.7(1)° associated with Ga(1). 2007 © The Japan Society for Analytical Chemistry. |
| spellingShingle | Coombs, N Aldridge, S Stasch, A Crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ- OGaI(OH)2}]2·3benzene |
| title | Crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ- OGaI(OH)2}]2·3benzene |
| title_full | Crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ- OGaI(OH)2}]2·3benzene |
| title_fullStr | Crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ- OGaI(OH)2}]2·3benzene |
| title_full_unstemmed | Crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ- OGaI(OH)2}]2·3benzene |
| title_short | Crystal structure of [{(η7-C7H7)Mo(CO)2Ga}2(μ-OGaI3){μ- OGaI(OH)2}]2·3benzene |
| title_sort | crystal structure of η7 c7h7 mo co 2ga 2 μ ogai3 μ ogai oh 2 2·3benzene |
| work_keys_str_mv | AT coombsn crystalstructureofē7c7h7moco2ga2mogai3mogaioh223benzene AT aldridges crystalstructureofē7c7h7moco2ga2mogai3mogaioh223benzene AT stascha crystalstructureofē7c7h7moco2ga2mogai3mogaioh223benzene |