STRUCTURE AND SUPERCONDUCTIVITY IN LITHIUM-INTERCALATED NIOBIUM DICHALCOGENIDES
The series LixNbS2 (0 ≤ x ≤ 0.50) and LixNbSe2 (0 ≤ x ≤ 0.67) have been prepared by high-temperature reaction of Li2S, Nb, and S or Li2Se, Nb, and Se. Structures have been determined by analysis of X-ray powder patterns with polytypism observed in the sulfide series. Evidence of staging and Li order...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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1985
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| _version_ | 1797090353420959744 |
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| author | Mcewen, C Stjulien, D Edwards, P Sienko, M |
| author_facet | Mcewen, C Stjulien, D Edwards, P Sienko, M |
| author_sort | Mcewen, C |
| collection | OXFORD |
| description | The series LixNbS2 (0 ≤ x ≤ 0.50) and LixNbSe2 (0 ≤ x ≤ 0.67) have been prepared by high-temperature reaction of Li2S, Nb, and S or Li2Se, Nb, and Se. Structures have been determined by analysis of X-ray powder patterns with polytypism observed in the sulfide series. Evidence of staging and Li ordering is reported, and crystal parameters are proposed for a second-staged sample, Li0.2NbSe2. In the series LixNbSe2, Tc exhibits a monotonic decrease with increasing lithium content, falling to less than 2 K by x = 0.25. In contrast, in the LixNbS2 series, Tc exhibits a more complicated pattern with Tc plummeting to below 2 K by x = 0.05, only to rebound to 3.7 K at x = 0.33 and then fall to below 2 K by x = 0.4. © 1985 American Chemical Society. |
| first_indexed | 2024-03-07T03:17:21Z |
| format | Journal article |
| id | oxford-uuid:b640e2da-db3c-4311-84e3-a155f58dd1ff |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:17:21Z |
| publishDate | 1985 |
| record_format | dspace |
| spelling | oxford-uuid:b640e2da-db3c-4311-84e3-a155f58dd1ff2022-03-27T04:39:34ZSTRUCTURE AND SUPERCONDUCTIVITY IN LITHIUM-INTERCALATED NIOBIUM DICHALCOGENIDESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b640e2da-db3c-4311-84e3-a155f58dd1ffEnglishSymplectic Elements at Oxford1985Mcewen, CStjulien, DEdwards, PSienko, MThe series LixNbS2 (0 ≤ x ≤ 0.50) and LixNbSe2 (0 ≤ x ≤ 0.67) have been prepared by high-temperature reaction of Li2S, Nb, and S or Li2Se, Nb, and Se. Structures have been determined by analysis of X-ray powder patterns with polytypism observed in the sulfide series. Evidence of staging and Li ordering is reported, and crystal parameters are proposed for a second-staged sample, Li0.2NbSe2. In the series LixNbSe2, Tc exhibits a monotonic decrease with increasing lithium content, falling to less than 2 K by x = 0.25. In contrast, in the LixNbS2 series, Tc exhibits a more complicated pattern with Tc plummeting to below 2 K by x = 0.05, only to rebound to 3.7 K at x = 0.33 and then fall to below 2 K by x = 0.4. © 1985 American Chemical Society. |
| spellingShingle | Mcewen, C Stjulien, D Edwards, P Sienko, M STRUCTURE AND SUPERCONDUCTIVITY IN LITHIUM-INTERCALATED NIOBIUM DICHALCOGENIDES |
| title | STRUCTURE AND SUPERCONDUCTIVITY IN LITHIUM-INTERCALATED NIOBIUM DICHALCOGENIDES |
| title_full | STRUCTURE AND SUPERCONDUCTIVITY IN LITHIUM-INTERCALATED NIOBIUM DICHALCOGENIDES |
| title_fullStr | STRUCTURE AND SUPERCONDUCTIVITY IN LITHIUM-INTERCALATED NIOBIUM DICHALCOGENIDES |
| title_full_unstemmed | STRUCTURE AND SUPERCONDUCTIVITY IN LITHIUM-INTERCALATED NIOBIUM DICHALCOGENIDES |
| title_short | STRUCTURE AND SUPERCONDUCTIVITY IN LITHIUM-INTERCALATED NIOBIUM DICHALCOGENIDES |
| title_sort | structure and superconductivity in lithium intercalated niobium dichalcogenides |
| work_keys_str_mv | AT mcewenc structureandsuperconductivityinlithiumintercalatedniobiumdichalcogenides AT stjuliend structureandsuperconductivityinlithiumintercalatedniobiumdichalcogenides AT edwardsp structureandsuperconductivityinlithiumintercalatedniobiumdichalcogenides AT sienkom structureandsuperconductivityinlithiumintercalatedniobiumdichalcogenides |