Homogeneous light-induced electron transfer between 9,10-anthracenedione and sodium tetraphenylborate: A channel electrode study
The electron transfer between excited-state 9,10-anthracenedione (325 nm) and sodium tetraphenylborate (tetraphenylboron sodium) in acetonitrile solution is shown to form the radical anion of 9,10-anthracenedione together with the BPhmath image radical. The latter is known to decompose to biphenyl a...
| Principais autores: | , , , |
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| Formato: | Journal article |
| Publicado em: |
1991
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| _version_ | 1826292638092886016 |
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| author | Compton, R Fisher, A Wellington, R Bethell, D |
| author_facet | Compton, R Fisher, A Wellington, R Bethell, D |
| author_sort | Compton, R |
| collection | OXFORD |
| description | The electron transfer between excited-state 9,10-anthracenedione (325 nm) and sodium tetraphenylborate (tetraphenylboron sodium) in acetonitrile solution is shown to form the radical anion of 9,10-anthracenedione together with the BPhmath image radical. The latter is known to decompose to biphenyl and other Products. A new channel electrode methodology is developed and characterized to deduce the mechanism of the reaction and to quantify its kinetics. |
| first_indexed | 2024-03-07T03:17:47Z |
| format | Journal article |
| id | oxford-uuid:b66208e1-607a-4ccd-82fa-05f065f95e5c |
| institution | University of Oxford |
| last_indexed | 2024-03-07T03:17:47Z |
| publishDate | 1991 |
| record_format | dspace |
| spelling | oxford-uuid:b66208e1-607a-4ccd-82fa-05f065f95e5c2022-03-27T04:40:35ZHomogeneous light-induced electron transfer between 9,10-anthracenedione and sodium tetraphenylborate: A channel electrode studyJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b66208e1-607a-4ccd-82fa-05f065f95e5cSymplectic Elements at Oxford1991Compton, RFisher, AWellington, RBethell, DThe electron transfer between excited-state 9,10-anthracenedione (325 nm) and sodium tetraphenylborate (tetraphenylboron sodium) in acetonitrile solution is shown to form the radical anion of 9,10-anthracenedione together with the BPhmath image radical. The latter is known to decompose to biphenyl and other Products. A new channel electrode methodology is developed and characterized to deduce the mechanism of the reaction and to quantify its kinetics. |
| spellingShingle | Compton, R Fisher, A Wellington, R Bethell, D Homogeneous light-induced electron transfer between 9,10-anthracenedione and sodium tetraphenylborate: A channel electrode study |
| title | Homogeneous light-induced electron transfer between 9,10-anthracenedione and sodium tetraphenylborate: A channel electrode study |
| title_full | Homogeneous light-induced electron transfer between 9,10-anthracenedione and sodium tetraphenylborate: A channel electrode study |
| title_fullStr | Homogeneous light-induced electron transfer between 9,10-anthracenedione and sodium tetraphenylborate: A channel electrode study |
| title_full_unstemmed | Homogeneous light-induced electron transfer between 9,10-anthracenedione and sodium tetraphenylborate: A channel electrode study |
| title_short | Homogeneous light-induced electron transfer between 9,10-anthracenedione and sodium tetraphenylborate: A channel electrode study |
| title_sort | homogeneous light induced electron transfer between 9 10 anthracenedione and sodium tetraphenylborate a channel electrode study |
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