Asymmetric Marcus theory: Application to electrode kinetics

The application of the simple Marcus-Hush (MH) formalism to fit the voltammetric experimental response of various solution-phase redox couples is unsuccessful. These and other experimental deviations have hitherto been tentatively attributed to differences of the force constants of the oxidized and...

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Bibliographic Details
Main Authors: Laborda, E, Henstridge, M, Compton, R
Format: Journal article
Language:English
Published: 2012