On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid

Hydroboration (using BH3) of 1-substituted 3-cyclopentenes 3, 9 and 17 and an enantioselective synthesis of the excitatory amino acid 1- aminocyclopentane-1,3-dicarboxylic acid via asymmetric hydroboration [90% de, 45% ee using (+)-IpcBH2] of cyclopentene 17 are described.

Bibliographic Details
Main Authors: Hodgson, D, Thompson, A, Wadman, S, Keats, C
Format: Journal article
Language:English
Published: 1999
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author Hodgson, D
Thompson, A
Wadman, S
Keats, C
author_facet Hodgson, D
Thompson, A
Wadman, S
Keats, C
author_sort Hodgson, D
collection OXFORD
description Hydroboration (using BH3) of 1-substituted 3-cyclopentenes 3, 9 and 17 and an enantioselective synthesis of the excitatory amino acid 1- aminocyclopentane-1,3-dicarboxylic acid via asymmetric hydroboration [90% de, 45% ee using (+)-IpcBH2] of cyclopentene 17 are described.
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spelling oxford-uuid:b7049ae5-7d43-4250-bece-988d2e7696f82022-03-27T04:45:28ZOn the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acidJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b7049ae5-7d43-4250-bece-988d2e7696f8EnglishSymplectic Elements at Oxford1999Hodgson, DThompson, AWadman, SKeats, CHydroboration (using BH3) of 1-substituted 3-cyclopentenes 3, 9 and 17 and an enantioselective synthesis of the excitatory amino acid 1- aminocyclopentane-1,3-dicarboxylic acid via asymmetric hydroboration [90% de, 45% ee using (+)-IpcBH2] of cyclopentene 17 are described.
spellingShingle Hodgson, D
Thompson, A
Wadman, S
Keats, C
On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid
title On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid
title_full On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid
title_fullStr On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid
title_full_unstemmed On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid
title_short On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid
title_sort on the possibility of carbamate directed hydroboration an approach to the asymmetric synthesis of 1 aminocyclopentane 1 3 dicarboxylic acid
work_keys_str_mv AT hodgsond onthepossibilityofcarbamatedirectedhydroborationanapproachtotheasymmetricsynthesisof1aminocyclopentane13dicarboxylicacid
AT thompsona onthepossibilityofcarbamatedirectedhydroborationanapproachtotheasymmetricsynthesisof1aminocyclopentane13dicarboxylicacid
AT wadmans onthepossibilityofcarbamatedirectedhydroborationanapproachtotheasymmetricsynthesisof1aminocyclopentane13dicarboxylicacid
AT keatsc onthepossibilityofcarbamatedirectedhydroborationanapproachtotheasymmetricsynthesisof1aminocyclopentane13dicarboxylicacid