On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid
Hydroboration (using BH3) of 1-substituted 3-cyclopentenes 3, 9 and 17 and an enantioselective synthesis of the excitatory amino acid 1- aminocyclopentane-1,3-dicarboxylic acid via asymmetric hydroboration [90% de, 45% ee using (+)-IpcBH2] of cyclopentene 17 are described.
Main Authors: | , , , |
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Format: | Journal article |
Language: | English |
Published: |
1999
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_version_ | 1826292764791275520 |
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author | Hodgson, D Thompson, A Wadman, S Keats, C |
author_facet | Hodgson, D Thompson, A Wadman, S Keats, C |
author_sort | Hodgson, D |
collection | OXFORD |
description | Hydroboration (using BH3) of 1-substituted 3-cyclopentenes 3, 9 and 17 and an enantioselective synthesis of the excitatory amino acid 1- aminocyclopentane-1,3-dicarboxylic acid via asymmetric hydroboration [90% de, 45% ee using (+)-IpcBH2] of cyclopentene 17 are described. |
first_indexed | 2024-03-07T03:19:44Z |
format | Journal article |
id | oxford-uuid:b7049ae5-7d43-4250-bece-988d2e7696f8 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T03:19:44Z |
publishDate | 1999 |
record_format | dspace |
spelling | oxford-uuid:b7049ae5-7d43-4250-bece-988d2e7696f82022-03-27T04:45:28ZOn the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acidJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b7049ae5-7d43-4250-bece-988d2e7696f8EnglishSymplectic Elements at Oxford1999Hodgson, DThompson, AWadman, SKeats, CHydroboration (using BH3) of 1-substituted 3-cyclopentenes 3, 9 and 17 and an enantioselective synthesis of the excitatory amino acid 1- aminocyclopentane-1,3-dicarboxylic acid via asymmetric hydroboration [90% de, 45% ee using (+)-IpcBH2] of cyclopentene 17 are described. |
spellingShingle | Hodgson, D Thompson, A Wadman, S Keats, C On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid |
title | On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid |
title_full | On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid |
title_fullStr | On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid |
title_full_unstemmed | On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid |
title_short | On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid |
title_sort | on the possibility of carbamate directed hydroboration an approach to the asymmetric synthesis of 1 aminocyclopentane 1 3 dicarboxylic acid |
work_keys_str_mv | AT hodgsond onthepossibilityofcarbamatedirectedhydroborationanapproachtotheasymmetricsynthesisof1aminocyclopentane13dicarboxylicacid AT thompsona onthepossibilityofcarbamatedirectedhydroborationanapproachtotheasymmetricsynthesisof1aminocyclopentane13dicarboxylicacid AT wadmans onthepossibilityofcarbamatedirectedhydroborationanapproachtotheasymmetricsynthesisof1aminocyclopentane13dicarboxylicacid AT keatsc onthepossibilityofcarbamatedirectedhydroborationanapproachtotheasymmetricsynthesisof1aminocyclopentane13dicarboxylicacid |