2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol.
The title mol-ecule, C(7)H(15)NO(5), the major product from selective enzymatic oxidation followed by hydrogeno-lysis of the corresponding azido-heptitol, was found by X-ray crystallography to exisit in a chair conformation with three axial hydroxyl groups. One of the hydroxymethyl groups is disorde...
| Auteurs principaux: | , , , , , , , , , |
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| Format: | Journal article |
| Langue: | English |
| Publié: |
2009
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| _version_ | 1826292807613022208 |
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| author | Jenkinson, S Booth, K Newberry, S Fleet, G Izumori, K Morimoto, K Nash, R Jones, L Watkin, D Thompson, A |
| author_facet | Jenkinson, S Booth, K Newberry, S Fleet, G Izumori, K Morimoto, K Nash, R Jones, L Watkin, D Thompson, A |
| author_sort | Jenkinson, S |
| collection | OXFORD |
| description | The title mol-ecule, C(7)H(15)NO(5), the major product from selective enzymatic oxidation followed by hydrogeno-lysis of the corresponding azido-heptitol, was found by X-ray crystallography to exisit in a chair conformation with three axial hydroxyl groups. One of the hydroxymethyl groups is disordered over two sets of sites in a 0.590 (3):0.410 (3) ratio. In the crystal, O-H⋯O, O-H⋯(O,O), O-H⋯N and N-H⋯O hydrogen bonding occurs. |
| first_indexed | 2024-03-07T03:20:23Z |
| format | Journal article |
| id | oxford-uuid:b737947d-c76b-464b-b402-614f723da1e8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:20:23Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:b737947d-c76b-464b-b402-614f723da1e82022-03-27T04:46:57Z2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b737947d-c76b-464b-b402-614f723da1e8EnglishSymplectic Elements at Oxford2009Jenkinson, SBooth, KNewberry, SFleet, GIzumori, KMorimoto, KNash, RJones, LWatkin, DThompson, AThe title mol-ecule, C(7)H(15)NO(5), the major product from selective enzymatic oxidation followed by hydrogeno-lysis of the corresponding azido-heptitol, was found by X-ray crystallography to exisit in a chair conformation with three axial hydroxyl groups. One of the hydroxymethyl groups is disordered over two sets of sites in a 0.590 (3):0.410 (3) ratio. In the crystal, O-H⋯O, O-H⋯(O,O), O-H⋯N and N-H⋯O hydrogen bonding occurs. |
| spellingShingle | Jenkinson, S Booth, K Newberry, S Fleet, G Izumori, K Morimoto, K Nash, R Jones, L Watkin, D Thompson, A 2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol. |
| title | 2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol. |
| title_full | 2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol. |
| title_fullStr | 2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol. |
| title_full_unstemmed | 2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol. |
| title_short | 2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol. |
| title_sort | 2 6 dide oxy 2 6 imino l glycero d ido heptitol |
| work_keys_str_mv | AT jenkinsons 26dideoxy26iminolglycerodidoheptitol AT boothk 26dideoxy26iminolglycerodidoheptitol AT newberrys 26dideoxy26iminolglycerodidoheptitol AT fleetg 26dideoxy26iminolglycerodidoheptitol AT izumorik 26dideoxy26iminolglycerodidoheptitol AT morimotok 26dideoxy26iminolglycerodidoheptitol AT nashr 26dideoxy26iminolglycerodidoheptitol AT jonesl 26dideoxy26iminolglycerodidoheptitol AT watkind 26dideoxy26iminolglycerodidoheptitol AT thompsona 26dideoxy26iminolglycerodidoheptitol |