Tuning main group redox chemistry through steric loading: subvalent Group 13 metal complexes of carbazolyl ligands.
The ability of substituted carbazol-9-yl systems to ligate in σ fashion through the amido N-donor, or to adopt alternative coordination modes through the π system of the central five-membered ring, can be tuned by systematic variation in the steric demands of substituents in the 1- and 8-positions....
المؤلفون الرئيسيون: | Mansaray, H, Kelly, M, Vidovic, D, Aldridge, S |
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التنسيق: | Journal article |
اللغة: | English |
منشور في: |
2011
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مواد مشابهة
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Synthesis and application of novel sterically demanding amido ligands in main group chemistry
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Coordination chemistry of group 13 monohalides
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