The mathematics of foam

The aim of this thesis is to derive and solve mathematical models for the flow of liquid in a foam. A primary concern is to investigate how so-called `Marangoni stresses' (i.e. surface tension gradients), generated for example by the presence of a surfactant, act to stabilise a foam. We aim to...

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Bibliographic Details
Main Author: Breward, C
Format: Thesis
Published: University of Oxford;Mathematical Institute 1999
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author Breward, C
author_facet Breward, C
author_sort Breward, C
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description The aim of this thesis is to derive and solve mathematical models for the flow of liquid in a foam. A primary concern is to investigate how so-called `Marangoni stresses' (i.e. surface tension gradients), generated for example by the presence of a surfactant, act to stabilise a foam. We aim to provide the key microscopic components for future foam modelling. We begin by describing in detail the influence of surface tension gradients on a general liquid flow, and various physical mechanisms which can give rise to such gradients. We apply the models thus devised to an experimental configuration designed to investigate Marangoni effects. Next we turn our attention to the flow in the thin liquid films (`lamellae') which make up a foam. Our methodology is to simplify the field equations (e.g. the Navier-Stokes equations for the liquid) and free surface conditions using systematic asymptotic methods. The models so derived explain the `stiffening' effect of surfactants at free surfaces, which extends considerably the lifetime of a foam. Finally, we look at the macroscopic behaviour of foam using an ad-hoc averaging of the thin film models.
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spelling oxford-uuid:b790abc8-a47e-4069-a2ac-f04de653f0322024-02-12T11:42:30ZThe mathematics of foamThesishttp://purl.org/coar/resource_type/c_db06uuid:b790abc8-a47e-4069-a2ac-f04de653f032Mathematical Institute - ePrintsUniversity of Oxford;Mathematical Institute1999Breward, CThe aim of this thesis is to derive and solve mathematical models for the flow of liquid in a foam. A primary concern is to investigate how so-called `Marangoni stresses' (i.e. surface tension gradients), generated for example by the presence of a surfactant, act to stabilise a foam. We aim to provide the key microscopic components for future foam modelling. We begin by describing in detail the influence of surface tension gradients on a general liquid flow, and various physical mechanisms which can give rise to such gradients. We apply the models thus devised to an experimental configuration designed to investigate Marangoni effects. Next we turn our attention to the flow in the thin liquid films (`lamellae') which make up a foam. Our methodology is to simplify the field equations (e.g. the Navier-Stokes equations for the liquid) and free surface conditions using systematic asymptotic methods. The models so derived explain the `stiffening' effect of surfactants at free surfaces, which extends considerably the lifetime of a foam. Finally, we look at the macroscopic behaviour of foam using an ad-hoc averaging of the thin film models.
spellingShingle Breward, C
The mathematics of foam
title The mathematics of foam
title_full The mathematics of foam
title_fullStr The mathematics of foam
title_full_unstemmed The mathematics of foam
title_short The mathematics of foam
title_sort mathematics of foam
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