WATER-SOLUBLE TRIS(HYDROXYMETHYL)PHOSPHINE COMPLEXES WITH NICKEL, PALLADIUM, AND PLATINUM - CRYSTAL-STRUCTURE OF [PD(P(CH2OH)3)4].CH3OH
The large-scale synthesis of the water-soluble phosphine P(CH2OH)3 (1) from either PH3 or [P(CH2OH)4]Cl is described. Treatment of [MX2(COD)] (M = Pt or Pd; X = Cl, Br, or I; COD = cycloocta-1,5-diene) with 1 gives the corresponding [MX2{P(CH2OH)3}2] (2-7) complexes which are soluble in water, metha...
| Hoofdauteurs: | , , , , , |
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| Formaat: | Journal article |
| Gepubliceerd in: |
1992
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