Chiral Phosphine-Phosphite Ligands with a Substituted Ethane Backbone. Influence of Conformational Effects in Rhodium-Catalyzed Asymmetric Olefin Hydrogenation and Hydroformylation Reactions

A family of chiral (3,3′-di-tert-butyl-5,5′,6,6′- tetramethyl-2,2′-biphenol-derived) phosphine-phosphite ligands (P-OP) with a substituted ethane backbone has been synthesized and the performance of these ligands in the Rh-catalyzed enantioselective hydrogenation and hydroformylation of several repr...

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Bibliografiska uppgifter
Huvudupphovsmän: Arribas, I, Vargas, S, Rubio, M, Suarez, A, Domene, C, Alvarez, E, Pizzano, A
Materialtyp: Journal article
Språk:English
Publicerad: 2010