A Stille cyclisation approach to (-)-periplanone-B: studies in alkene-selective ring-closing metathesis and an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydes
A synthesis of the dienone 7 via an efficient intramolecular Stille cross-coupling reaction, an improved chromium(n)mediated synthesis of (£)-alkenylstannanes from aldehydes using Bu3SnCHI2 in DMF, and a synthesis of the substituted (-)-dienone 25 via ring-closing alkene metathesis to give dihydropy...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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1999
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| _version_ | 1797090914042118144 |
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| author | Hodgson, D Foley, A Boulton, LT Lovell, P Maw, G |
| author_facet | Hodgson, D Foley, A Boulton, LT Lovell, P Maw, G |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | A synthesis of the dienone 7 via an efficient intramolecular Stille cross-coupling reaction, an improved chromium(n)mediated synthesis of (£)-alkenylstannanes from aldehydes using Bu3SnCHI2 in DMF, and a synthesis of the substituted (-)-dienone 25 via ring-closing alkene metathesis to give dihydropyran 22 are described. The synthesis of (-)-dienone 25 constitutes a formal synthesis of (-)-periplanone-B. © The Royal Society of Chemistry 1999. |
| first_indexed | 2024-03-07T03:25:29Z |
| format | Journal article |
| id | oxford-uuid:b8e34238-deae-4500-8b23-cfeb0e3ec6ff |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:25:29Z |
| publishDate | 1999 |
| record_format | dspace |
| spelling | oxford-uuid:b8e34238-deae-4500-8b23-cfeb0e3ec6ff2022-03-27T04:59:06ZA Stille cyclisation approach to (-)-periplanone-B: studies in alkene-selective ring-closing metathesis and an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b8e34238-deae-4500-8b23-cfeb0e3ec6ffEnglishSymplectic Elements at Oxford1999Hodgson, DFoley, ABoulton, LTLovell, PMaw, GA synthesis of the dienone 7 via an efficient intramolecular Stille cross-coupling reaction, an improved chromium(n)mediated synthesis of (£)-alkenylstannanes from aldehydes using Bu3SnCHI2 in DMF, and a synthesis of the substituted (-)-dienone 25 via ring-closing alkene metathesis to give dihydropyran 22 are described. The synthesis of (-)-dienone 25 constitutes a formal synthesis of (-)-periplanone-B. © The Royal Society of Chemistry 1999. |
| spellingShingle | Hodgson, D Foley, A Boulton, LT Lovell, P Maw, G A Stille cyclisation approach to (-)-periplanone-B: studies in alkene-selective ring-closing metathesis and an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydes |
| title | A Stille cyclisation approach to (-)-periplanone-B: studies in alkene-selective ring-closing metathesis and an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydes |
| title_full | A Stille cyclisation approach to (-)-periplanone-B: studies in alkene-selective ring-closing metathesis and an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydes |
| title_fullStr | A Stille cyclisation approach to (-)-periplanone-B: studies in alkene-selective ring-closing metathesis and an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydes |
| title_full_unstemmed | A Stille cyclisation approach to (-)-periplanone-B: studies in alkene-selective ring-closing metathesis and an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydes |
| title_short | A Stille cyclisation approach to (-)-periplanone-B: studies in alkene-selective ring-closing metathesis and an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydes |
| title_sort | stille cyclisation approach to periplanone b studies in alkene selective ring closing metathesis and an improved chromium ii mediated synthesis of e alkenylstannanes from aldehydes |
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