Copper(II)-directed synthesis of neutral heteroditopic [2]rotaxane ion-pair host systems incorporating hydrogen and halogen bonding anion binding cavities
Neutral heteroditopic [2]rotaxane ion-pair host systems were synthesised via a Cu(II) directed passive metal template strategy. Each rotaxane contains discrete, axle-separated interlocked binding sites for a guest anion and a transition metal countercation. The anion binding sites are composed of co...
| Main Authors: | , , , , |
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| Format: | Journal article |
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Royal Society of Chemistry
2017
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| _version_ | 1826293168910368768 |
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| author | Brown, A Mennie, K Mason, O White, N Beer, P |
| author_facet | Brown, A Mennie, K Mason, O White, N Beer, P |
| author_sort | Brown, A |
| collection | OXFORD |
| description | Neutral heteroditopic [2]rotaxane ion-pair host systems were synthesised via a Cu(II) directed passive metal template strategy. Each rotaxane contains discrete, axle-separated interlocked binding sites for a guest anion and a transition metal countercation. The anion binding sites are composed of convergent X–H (X = C, N) hydrogen bond donor groups, or mixed X–H and C–I hydrogen and halogen bond donor groups, whereas an equivalent three-dimensional array of amine, pyridine and carbonyl oxygen donor groups comprise the transition metal binding site. 1H NMR titrations experiments in CDCl3/CD3OD or CDCl3/CD3OD/D2O solvent mixtures reveal that the heteroditopic [2]rotaxane host systems are capable of cooperative anion recognition in the presence of a co-bound Zn(II) cation. |
| first_indexed | 2024-03-07T03:25:57Z |
| format | Journal article |
| id | oxford-uuid:b9098c00-e100-4590-9346-895eccaef0cc |
| institution | University of Oxford |
| last_indexed | 2024-03-07T03:25:57Z |
| publishDate | 2017 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:b9098c00-e100-4590-9346-895eccaef0cc2022-03-27T05:00:09ZCopper(II)-directed synthesis of neutral heteroditopic [2]rotaxane ion-pair host systems incorporating hydrogen and halogen bonding anion binding cavitiesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b9098c00-e100-4590-9346-895eccaef0ccSymplectic Elements at OxfordRoyal Society of Chemistry2017Brown, AMennie, KMason, OWhite, NBeer, PNeutral heteroditopic [2]rotaxane ion-pair host systems were synthesised via a Cu(II) directed passive metal template strategy. Each rotaxane contains discrete, axle-separated interlocked binding sites for a guest anion and a transition metal countercation. The anion binding sites are composed of convergent X–H (X = C, N) hydrogen bond donor groups, or mixed X–H and C–I hydrogen and halogen bond donor groups, whereas an equivalent three-dimensional array of amine, pyridine and carbonyl oxygen donor groups comprise the transition metal binding site. 1H NMR titrations experiments in CDCl3/CD3OD or CDCl3/CD3OD/D2O solvent mixtures reveal that the heteroditopic [2]rotaxane host systems are capable of cooperative anion recognition in the presence of a co-bound Zn(II) cation. |
| spellingShingle | Brown, A Mennie, K Mason, O White, N Beer, P Copper(II)-directed synthesis of neutral heteroditopic [2]rotaxane ion-pair host systems incorporating hydrogen and halogen bonding anion binding cavities |
| title | Copper(II)-directed synthesis of neutral heteroditopic [2]rotaxane ion-pair host systems incorporating hydrogen and halogen bonding anion binding cavities |
| title_full | Copper(II)-directed synthesis of neutral heteroditopic [2]rotaxane ion-pair host systems incorporating hydrogen and halogen bonding anion binding cavities |
| title_fullStr | Copper(II)-directed synthesis of neutral heteroditopic [2]rotaxane ion-pair host systems incorporating hydrogen and halogen bonding anion binding cavities |
| title_full_unstemmed | Copper(II)-directed synthesis of neutral heteroditopic [2]rotaxane ion-pair host systems incorporating hydrogen and halogen bonding anion binding cavities |
| title_short | Copper(II)-directed synthesis of neutral heteroditopic [2]rotaxane ion-pair host systems incorporating hydrogen and halogen bonding anion binding cavities |
| title_sort | copper ii directed synthesis of neutral heteroditopic 2 rotaxane ion pair host systems incorporating hydrogen and halogen bonding anion binding cavities |
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