Cationic terminal aminoborylene complexes: controlled stepwise insertion into M=B and B=N double bonds.

(Chemical Equation Presented) One thing leads to another: Reactions of the cationic BN vinylidene analogues 1-[BArF4] (R = Cy, iPr; ArF = 3,5-(CF3)2C6H3) towards dicyclohexylcarbodiimide proceed by unprecedented insertion chemistry for terminal borylene complexes. Controlled, stepwise insertion into...

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Hlavní autoři: Pierce, G, Aldridge, S, Jones, C, Gans-Eichler, T, Stasch, A, Coombs, N, Willock, D
Médium: Journal article
Jazyk:English
Vydáno: 2007