Development of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes.
Radical thiol additions to 7-azanorbornadienes give 7-thio-substituted 2-azanorbornenes and Barton deoxygenations of 7-azabenzonorbornanols give 2-azabenzonorbornanes. The processes both involve novel nitrogen-directed radical rearrangements. The kinetics and mechanisms of the reactions are also dis...
| Main Authors: | , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2003
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| _version_ | 1826293247450808320 |
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| author | Hodgson, D Bebbington, M Willis, P |
| author_facet | Hodgson, D Bebbington, M Willis, P |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | Radical thiol additions to 7-azanorbornadienes give 7-thio-substituted 2-azanorbornenes and Barton deoxygenations of 7-azabenzonorbornanols give 2-azabenzonorbornanes. The processes both involve novel nitrogen-directed radical rearrangements. The kinetics and mechanisms of the reactions are also discussed. |
| first_indexed | 2024-03-07T03:27:10Z |
| format | Journal article |
| id | oxford-uuid:b9736f5c-a74e-4fd8-aa85-b818cf0616c3 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:27:10Z |
| publishDate | 2003 |
| record_format | dspace |
| spelling | oxford-uuid:b9736f5c-a74e-4fd8-aa85-b818cf0616c32022-03-27T05:03:03ZDevelopment of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b9736f5c-a74e-4fd8-aa85-b818cf0616c3EnglishSymplectic Elements at Oxford2003Hodgson, DBebbington, MWillis, PRadical thiol additions to 7-azanorbornadienes give 7-thio-substituted 2-azanorbornenes and Barton deoxygenations of 7-azabenzonorbornanols give 2-azabenzonorbornanes. The processes both involve novel nitrogen-directed radical rearrangements. The kinetics and mechanisms of the reactions are also discussed. |
| spellingShingle | Hodgson, D Bebbington, M Willis, P Development of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes. |
| title | Development of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes. |
| title_full | Development of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes. |
| title_fullStr | Development of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes. |
| title_full_unstemmed | Development of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes. |
| title_short | Development of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes. |
| title_sort | development of two processes for the synthesis of bridged azabicyclic systems intermolecular radical addition homoallylic rearrangements leading to 2 azanorborn 5 enes and neophyl type radical rearrangements to 2 azabenzonorbornanes |
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