The use of differential pulse voltammetries to discriminate between the Butler-Volmer and the simple Marcus-Hush models for heterogeneous electron transfer: The electro-reduction of europium (III) in aqueous solution

Differential multipulse voltammetry and square wave voltammetry are employed to critically compare and discriminate between the Butler-Volmer and Marcus-Hush kinetic formalisms of heterogeneous electron transfer. The reduction of europium (III) in aqueous solution is studied with mercury hemispheric...

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Bibliographic Details
Main Authors: Wang, Y, Laborda, E, Henstridge, M, Martinez-Ortiz, F, Molina, A, Compton, R
Format: Journal article
Language:English
Published: 2012