Acid-promoted rearrangement of carbonate functionality anchored to the lower rim of a calix[4]arene skeleton: A new class of chiral calix[4]arene and its chiroptical properties
(equation presented) A unique calix[4]arene lower-rim intramolecular rearrangement, resulting in molecular asymmetry arising from the upper- and lower-rim substitution pattern, produces a new class of inherently chiral calix[4]arenes in a partial cone conformation. This was aided by molecular rigidi...
Main Authors: | Hesek, D, Inoue, Y, Drew, M, Beer, P, Hembury, G, Ishida, H, Aoki, F |
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Format: | Journal article |
Language: | English |
Published: |
2000
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