Acid-promoted rearrangement of carbonate functionality anchored to the lower rim of a calix[4]arene skeleton: A new class of chiral calix[4]arene and its chiroptical properties

Acid-promoted rearrangement of carbonate functionality anchored to the lower rim of a calix[4]arene skeleton: A new class of chiral calix[4]arene and its chiroptical properties

(equation presented) A unique calix[4]arene lower-rim intramolecular rearrangement, resulting in molecular asymmetry arising from the upper- and lower-rim substitution pattern, produces a new class of inherently chiral calix[4]arenes in a partial cone conformation. This was aided by molecular rigidi...

Полное описание

Библиографические подробности
Главные авторы:	Hesek, D, Inoue, Y, Drew, M, Beer, P, Hembury, G, Ishida, H, Aoki, F
Формат:	Journal article
Язык:	English
Опубликовано:	2000

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