Development of functional group tolerant and room temperature hydrogen borrowing enolate alkylation reactions

Development of functional group tolerant and room temperature hydrogen borrowing enolate alkylation reactions

<p>This thesis describes work completed to expand the scope of hydrogen borrowing enolate alkylation reactions. It was hypothesised that the development of a room temperature reaction would allow utility of a breadth of chemical space previously undemonstrated in these reactions at high temper...

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Bibliografiske detaljer
Hovedforfatter:	Bailey, EP
Andre forfattere:	Smith, M
Format:	Thesis
Sprog:	English
Udgivet:	2023
Fag:	Enolate Alkylation Hydrogen Borrowing Borrowing Hydrogen Iridium Catalysis Ketone Alkylation Chemistry, Organic Alcohols Organometallic chemistry Organic Chemistry Methodology Mechanism Iridium hydrides Homogeneous catalysis Photochemistry Ketones Mechanistic Studies

Lignende værker

Ligand‐Promoted [Pd]‐Catalyzed α‐Alkylation of Ketones through a Borrowing‐Hydrogen Approach
af: Dr. Seetharaman Manojveer, et al.
Udgivet: (2023-01-01)

The Allylic Alkylation of Ketone Enolates
af: Dr. Lukas Junk, et al.
Udgivet: (2020-09-01)

Metal-ligand cooperative iridium complex catalyzed C-alkylation of oxindole and 1,3-dimethylbarbituric acid using alcohols
af: Ao Song, et al.
Udgivet: (2023-08-01)

Synergistic copper-aminocatalysis for direct tertiary 𝜶-alkylation of ketones with electron-deficient alkanes
af: Shan, Qi-Chao, et al.
Udgivet: (2024)

Iridium-Catalyzed and pH-Dependent Reductions of Nitroalkenes to Ketones
af: Tingting Wang, et al.
Udgivet: (2022-11-01)

Self‐Suspended Nanoparticles for N‐Alkylation Reactions: A New Concept for Catalysis
af: Prof. Maria Sarno, et al.
Udgivet: (2019-04-01)

Gold-catalyzed alkylation of silyl enol ethers with ortho-alkynylbenzoic acid esters
af: Haruo Aikawa, et al.
Udgivet: (2011-05-01)

Ruthenacycles and Iridacycles as Transfer Hydrogenation Catalysts
af: Vincent Ritleng, et al.
Udgivet: (2021-07-01)

Manganese-catalyzed C–C and C–N bond formation with alcohols via borrowing hydrogen or hydrogen auto-transfer
af: Mohd Farhan Ansari, et al.
Udgivet: (2024-05-01)

Recent developments in transition metal-catalyzed asymmetric borrowing hydrogen catalysis
af: Nidhi Garg, et al.
Udgivet: (2023-12-01)

Palladium-catalysed heterocycle synthesis
af: Sadig, JER
Udgivet: (2012)

Recent Achievements in Enantioselective Borrowing Hydrogen by the Combination of Iron- and Organocatalysis
af: Mylène Roudier, et al.
Udgivet: (2016-02-01)

Comparison of Iridium(I) Catalysts in Temperature Mediated Hydrogen Isotope Exchange Reactions
af: Mégane Valero, et al.
Udgivet: (2019-09-01)

Catalytic asymmetric carbon-carbon bond formation using alkenes as alkylmetal equivalents
af: Maksymowicz, R
Udgivet: (2014)

Development of catalytic methods to exploit sulfur dioxide in organic synthesis
af: Emmett, EJ
Udgivet: (2014)

Asymmetric conjugate additions of alkylzirconocenes to cyclopent-4-ene-1,3-dione monoacetals.
af: Rideau, E, et al.
Udgivet: (2015)

GROUP III permethylindenyl-phenoxy complexes for biorenewable polymer synthesis
af: Hayden, JA
Udgivet: (2024)

Supported heteropolyacid (HPW) catalysts for the continuaus alkylation of isobutane with 2 butene : the benefit of using MCM-41 with larger pore diameters /
af: Blasco, T.

Palladium-catalyzed enantioselective arylation of racemic ketones to form bridged bicycles via dynamic kinetic resolution
af: Huang, Xiaolei, et al.
Udgivet: (2019)

Ir-Catalyzed Reduction of Carbonyl Compounds Using Biogenetic Alcohols
af: Yuta Nishina
Udgivet: (2019-09-01)

Discovery and development of ferrocene-based tetradentate ligands for Ir-catalysed asymmetric hydrogenation of ketone
af: Jianfei Yu, et al.
Udgivet: (2022-05-01)

Studies towards the nucleophilic dearomatisation of electron-deficient heteroaromatics and hydrogen borrowing reactions of methanol
af: Poole, DL
Udgivet: (2014)

Enantioselective synthesis and reactivity of benzylic fluorides
af: Blessley, G, et al.
Udgivet: (2013)

Palladium-catalysed enolate arylation in the synthesis of isoquinolines
af: Gatland, A, et al.
Udgivet: (2014)

Palladium-Catalyzed Arylation of Ketones and Acetonitrile with Ortho Alkylation of Aryl Rings: De Novo Synthesis of Tetralines and Benzocycloheptenes
af: Lei, Chuanhu, et al.
Udgivet: (2017)

Heteroatom-substituted bicyclo[1.1.1]pentanes
af: Pickford, H
Udgivet: (2022)

Chiral Phosphoric Acid Diesters as Ligands in Asymmetric Transition Metal Catalyzed Hydrogenation
af: Manfred T. Reetz, et al.
Udgivet: (2003-05-01)

The synthesis and study of titanium amidinate complexes as olefin polymerisation catalysts
af: Scharbert, MT
Udgivet: (2018)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
af: Pernik, I
Udgivet: (2014)

Radical coupling of β-ketoesters and amides promoted by Brønsted/Lewis acids
af: Joshua L. Zhu, et al.
Udgivet: (2020-06-01)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
af: Ylioja, P
Udgivet: (2011)

Development of bifunctional organic superbases for catalytic enantioselective synthesis
af: Rozsar, D
Udgivet: (2024)

Palladium-catalyzed asymmetric allylic alkylations of colby pro-enolates with MBH carbonates : enantioselective access to quaternary C-F oxindoles
af: Zhu, Yi, et al.
Udgivet: (2020)

Exploring the reactivity patterns of cationic and neutral rhodium bis-phosphine species with amine-boranes
af: Sewell, LJ
Udgivet: (2013)

Alkaline earth and rare earth complexes for the ring opening polymerisation of cyclic esters
af: Clark, L
Udgivet: (2012)

Cationic rhodium complexes with chelating phosphine and phosphine alkene ligands. Application in dehydrogenation and dehydrocoupling reactions
af: Dallanegra, R
Udgivet: (2011)

Surface and interfacial organometallic chemistry and catalysis /
af: Chaudret, Bruno
Udgivet: (2005)

Palladium-catalyzed para-selective alkylation of electron-deficient arenes
af: Jiao, Zhiwei, et al.
Udgivet: (2019)

Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations
af: Zhihong Deng, et al.
Udgivet: (2020-08-01)

Reactions of allenylpalladium intermediates in organic synthesis
af: Daniels, DSB
Udgivet: (2013)