Reactivity of Cationic Terminal Borylene Complexes: Novel Mechanisms for Insertion and Metathesis Chemistry Involving Strongly Lewis Acidic Ligand Systems

The reactions of terminal borylene complexes of the type [CpFe(CO) 2(BNR2)]+ (R = i1Pr, Cy) with heteroallenes have been investigated by quantum-chemical methods, in an attempt to explain the experimentally observed product distributions. Reaction with dicyclohexylcarbodiimide (CyNCNCy) gives a bis-...

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Príomhchruthaitheoirí: De, S, Pierce, G, Vidovic, D, Kays, D, Coombs, N, Jemmis, E, Aldridge, S
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 2009